Mike Engelhardt (BRUKER),
Mark.Dixon@charnwood.gb.astra.com,
bill.eberle@cp.Novartis.com,
"Sato, Bob" <RKS@mv.catalytica-inc.com>,
"J. W. Emsley" <J.W.Emsley@soton.ac.uk>,
Stefan Berger <stberger@rz.uni-leipzig.de>,
and Lawrence Byrnes <numare@eclipse.net>.
*****************************************
This was my question:
*****************************************
Date: Wed, 20 Jan 1999 14:55:14 +0100
Subject: 31P shift tables
Dear BUMERs,
does anyone know of extensive 31P NMR chemical shift
tables in a review or a book*? Specifically, I am looking for
chemical shifts as seen in aqueous solution at around pH 7.
such as signals appearing in the region of phenyl-phosphinate
(roughly at about 20 ppm when inorganic phosphate and
sugar phosphates appear at about 0 to 5 ppm, pH 7,
aqueous solution). That these signals belong to phenyl-
phosphinate or a related compound is unlikely.
*: I know of Crutchfield et al. 1967. 31P Nuclear
Magnetic Resonance, John Wiley. But I am looking for
something more recent and more in the "aqueous
solution at pH 7" range.
*************************************************
And these are the papers/books that were recommended:
*************************************************
I use the "Handbook of Phosphorus-31 Nuclear Magnetic Resonance Data" edited
by John C. Tebby.
Published by CRC Press in 1991, ISBN 0-8493-3531-0
It has shifts of every conceivable 31-P molecule and in more solvents than I
have ever imagined possible.
Each listing has the literature reference.
***
You might find David Gorenstein's book Phosphorous-31 NMR Principles and
Applications to be of some use. My copy is dated 1984, but I am sure that
there is a more recent edition.
I am not sure what you are studying, but thiophosphate esters and other
agrochemicals such as glyphosate (Monsanto's RoundUp) have chemical shifts
in the 10 to 30 ppm range.
***
I don't know if this book will specifically answer your question, but ...
Phosphorus-31 NMR: Principles and Applications
Davis G. Gorenstein, Academic Press, 1984.
"J. W. Emsley" <J.W.Emsley@soton.ac.uk>
Try David Gorenstein's article in Prog. Nucl. Magn. Reson.,
vol 16, 1 (1985)
***
NMR Spectroscopy of the Non-Metallic Elements, (English)
Stefan Berger, Siegmar Braun, Hans-Otto Kalinowski,
John Wiley & Sons, Ltd., 1997,
ISBN 0 471 96763 7
from:
NMR-Spektroskopie von Nichmetallen,
Georg Thieme Verlag, 1992, 1993, and 1994
http://www.uni-leipzig.de/~nmr/STB/stb.html Date: Wed, 20
Thanks again,
Siegfried Schoberth
+-----------------------------------
| Siegfried M. Schoberth (PhD)
| Institute of Biotechnology 1
| research Center Juelich (FZJ)
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