PP Presentation

GAS FORMING REACTIONS - alternative classification

A. CaCO3 (s) + 3 HCl (aq) ® CaCl2 (aq) + H2O (l) + CO2 (g) ­

There is no precipitate and no change in O.N. (Ca stays as +2, Cl as -1)

It is an ACID-BASE REACTION involving an intermediate H2CO3

called CARBONIC ACID, which immediately dissociates to H2O and CO2

2 H+ + CO32- ® “H2CO3 “ ® H2O + CO2 ­

B. Zn (s) + 2 HCl (aq) ® ZnCl2 (aq) + H2 (g) ­

There is no precipitate. However there is an obvious change in O.N.

It is also an example of an OXIDATION-REDUCTION REACTION

Zn goes from O.N. = 0 in the metal to O.N. = +2 in the chloride salt

H goes from O.N. = +1 in HCl (aq) to O.N. = 0 in the elemental gas

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